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Product Details
Product Name | Hexylamine |
Alias | 1-Aminohexane;1-hexanamine;hexan-1-amine |
English | |
Molecular formula | C6H15N |
Molecular weight | 101.19 |
CAS No | 111-26-2 |
EINECS | |
Specification | Assay(GC)99% Moisture content < 0.3% color < 30 # (APHA) |
Appearance traits | |
Use | It Mainly used as the intermediate of dye, pigment, surfactant and pharmaceutical synthesis. |
Package | 160kg/drum |
Other product information | Properties: Appearance:Colorless liquid with ammonia flavor, Melting point:−23 °C(lit.) Boiling point:131 °C(lit.) Density:0.766 g/ml at 25 °C(lit.) Refractive index:N20/D 1.422(lit.) Flash(ing) point:8.9°C Water soluble properties:14 g/L (20 ºc) Sensibility:Air sensitive |
Synthesis Reference(s) |
The Journal of Organic Chemistry, 55, p. 2271, 1990 DOI: 10.1021/jo00295a002Synthesis, p. 605, 1981 |
Air & Water Reactions |
Highly flammable. Slightly soluble in water. |
Reactivity Profile |
HEXYLAMINE neutralize acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. |
Health Hazard |
Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. |
Flammability and Explosibility |
Flammable |
Purification Methods |
Dry with, and fractionally distil the hexylamine from, KOH or CaH2. Store away from CO2. [Beilstein 4 IV 709.] |
Definition |
ChEBI: A 6-carbon primary aliphatic amine. |
Aroma threshold values |
High strength odor; fishy type, recommend smelling in a 0.10% solution or less |
General Description |
A water-white liquid with an amine-like odor. Flash point 85°F. Boiling point 132°F. Less dense than water and poorly soluble in swater. Hence floats on water. May be toxic by inhalation, ingestion or skin absorption. |
InChI:InChI=1/C6H15N/c1-2-3-4-5-6-7/h2-7H2,1H3/p+1
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complex of α-cyclodextrin with n-hexylamine
hexan-1-amine
alpha cyclodextrin
Conditions | Yield |
---|---|
With phosphate buffer; In water-d2; at 25 ℃; Equilibrium constant; Thermodynamic data; standard molar enthalpy ΔrH0, standard molar Gibbs energy ΔrG0, standard molar entropy ΔrS0;
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In alkaline aq. solution; at 25 ℃; pH=11.60; Equilibrium constant;
|
N-hexylbenzamide
hexan-1-amine
benzyl alcohol
Conditions | Yield |
---|---|
With Ag/γ-Al2O3 (2.5 mol%); potassium tert-butylate; hydrogen; In 1,4-dioxane; at 150 ℃; for 48h; under 37503.8 Torr; chemoselective reaction; Green chemistry;
|
72 %Spectr. 70 %Spectr. |
With potassium tert-butylate; hydrogen; [Ru(PtBuNNHBn)H(CO)Cl]; In tetrahydrofuran; at 35 ℃; for 68h; under 7500.75 Torr;
|
63 %Chromat. 62 %Chromat. |
1-hexyl-2-methyl-pyrrole
chromium(lll) acetate
hexanenitrile
octan-2-one oxime
2-(hexylamino)ethan-1-ol
2-[hexyl-(2-hydroxyethyl)amino]ethanol
2-Hexylamino-ethylmercaptan
1-hexyl-2,5-pyrrolidinedione
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